Product ID:FOTOFOIL DEVELOPER
MSDS Date:08/27/1986
FSC:6740
NIIN:00F019834
MSDS Number: BLRCM

MILLER DIAL CORP/FOTOFOIL DIVISION

4400 NORTH TEMPLE CITY BLVD
EL MONTE, CA 91731

Emergency Phone: (818) 444-4565

Info Phone: (818) 444-4565

Cage: 91345

MILLER DIAL CORP FOTOFOIL DIVISION

EL MONTE, CA 91731 US

Cage: 91345

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 80%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 20%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT): 10 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT/RESPIRATORY
TRACT IRRITATION/CNS DEPRESSION/LIVER/KIDNEY EFFECTS. SKIN:
IRRITATION/REDNESS/ROUGHNESS/DRYNESS/DERMATITIS/BURNING SENSATION.
EYES: IRRITATION/BURNING SENSATION/TE ARING/INFLAMMATION/BLURRED
VISION. INGESTION: TOXIC/HARMFUL/GASTROINTESTINAL
IRRITATION/NAUSEA/VOMITING/DIARRHEA.
Explanation of Carcinogenicity:METHYLENE CHLORIDE IS A SUSPECTED HUMAN
CARCINOGEN.
Effects of Overexposure:INHALATION: NOSE/THROAT/RESPIRATORY TRACT
IRRITATION/CNS DEPRESSION/LIVER/KIDNEY EFFECTS. SKIN:
IRRITATION/REDNESS/ROUGHNESS/DRYNESS/DERMATITIS/BURNING SENSATION.
EYES: IRRITATION/BURNING SENSATION/TE EARING/INFLAMMATION/BLURRED
VISION. INGESTION: TOXIC/HARMFUL/GASTROINTESTINAL
IRRITATION/NAUSEA/VOMITING/DIARRHEA.
Medical Cond Aggravated by Exposure:SKIN, EYE & RESPIRATORY DISORDERS.

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/WATER. FOLLOW
BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE
OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. INGESTION: DON'T INDUCE
VOMITI NG. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS
TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS MAY CAUSE CHEMICAL
PNEUMONITIS. OBTAIN MED ATTN IN ALL CASES. NOTE TO PHYSICIAN: SEE
SUPP.

Flash Point:NONE
Upper Limits:23%
Extinguishing Media:WATER FOG, DRY CHEMICAL, OR CO2
Fire Fighting Procedures:WEAR SCBA IN PRESSURE DEMAND. USE WATER SPRAY
TO KEEP HEAT/FIRE EXPOSED CONTAINERS COOL TO PREVENT PRESSURE
BUILD-UP/PRESSURE/WEAKENING OF CONTAINER STRUCTURE.
Unusual Fire/Explosion Hazard:VAPORS ARE >AIR & WILL COLLECT IN LOW
AREAS SUCH AS PITS/DEGREASERS/STORAGE TANKS/CONFINED AREAS. PRODUCT
AEROSOLS MAY BE FLAMMABLE OR EXPLOSIVE.

Spill Release Procedures:EVACUATE/VENTILATE AREA. DIKE AREA TO CONTAIN
SPILL. CLEAN UP AREA BY MOPPING OR W/ABSORBENT MATERIAL & PLACE IN
CLOSED CONTAINERS FOR DISPOSAL. DON'T FLUSH TO SEWER. WEAR
PROTECTIVE EQUIPMENT.

Handling and Storage Precautions:HANDLE W/REASONABLE CARE & CAUTION.
STORE DRUMS IN A COOL PLACE, BUNG UP & TIGHTLY CLOSED. DRUMS SHOULD
BE VENTED FOR FILLING & PRESSURE EQUALIZATION.
Other Precautions:VENTS FROM INDOOR TANKS SHOULD TERMINATE OUTDOORS.
AVOID BREATHING VAPORS/CONTACT W/SKIN. DON'T EAT/DRINK/SMOKE IN
WORK AREA. INTENTIONAL ABUSE/MISUSE/OTHER MASSIVE EXPOSURE MAY
RESULT IN DIFFICULT BR EATHING/NAUSEA/VOMIT/HEADACHE/COMA/DEATH

Respiratory Protection:IF >TLV, USE A NIOSH APPROVED RESPIRATOR TO
PREVENT OVER EXPOSURE. USE EITHER A FULL-FACE, ATMOSPHERE-SUPPLYING
RESPIRATOR OR AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:TO KEEP Protective Gloves:RECOMMENDED
Eye Protection:SAFETY GLASSES, CHEMICAL GOGGLES
Other Protective Equipment:CLEAN BODY COVERING CLOTHING, BOOTS, APRON
OR FULL BODY SUIT.
Work Hygienic Practices:WASH HANDS PRIOR TO EATING/DRINKING/USING
RESTROOM. REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE.
Supplemental Safety and Health
PHYSICIAN NOTE: THE DECISION OF WHETHER TO INDUCE VOMITING OR NOT
SHOULD BE MADE BY THE PHYSICIAN. IF LAVAGE IS PERFOMED, SUGGEST
ENDOTRACHEAL/ESOPHAGEAL CONTROL. IF BURNED, TREAT AS A THERMAL
BURN, A FTER DECONTAMINATION. DON'T ADMINISTER DRUGS UNLESS
ABSOLUTELY NECESSARY. NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE.

Boiling Pt:B.P. Text:104-165F
Vapor Pres:184
Vapor Density:4.23
Evaporation Rate & Reference:(N-BU AC = 1): 1.2
Solubility in Water:0.3%
Appearance and Odor:CLEAR COLORLESS LIQUID W/CHLOROFORM LIKE ODOR.
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
BARIUM, LITHIUM, MAGNESIUM, TITANIUM, STRONG OXIDIZING AGENTS, STRONG
ALKALIES, STRONG MINERAL ACIDS & ALUMINUM.
Stability Condition to Avoid:DIRECT FLAME, INTENSE HEAT
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS/HYDROCHLORIC
ACID GAS/SMALL QUANTITIES OF OTHER TOXIC & IRRITATING VAPORS/GASES
SUCH AS PHOSGENE

Waste Disposal Methods:SENT RECOVERED LIQUIDS TO A
LICENSED/INCINERATION FACILITY. DISPOSE CONTAMINATED MATERIAL IN A
HAZARDOUS WASTE MANAGEMENT FACILITY. CONSULT FEDERAL, STATE, LOCAL
DISPOSAL AUTHORITIES FOR APPROVED PROC EDURES. DON'T CONTAMINATE
GROUND & SURFACE WATERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.